Product ID:48411 FREON 113/1X1ML/MEOH/1000UG/ML
MSDS Date:02/03/1994
FSC:6810
NIIN:00F037600
MSDS Number: BWJLT

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 0.1%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL 260 MG/CUM

ACGIH TLV: 262 MG/CUM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG METHANOL
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL. INGESTION: FATAL.
GASTROINTESTINAL DISTURBANCES. EYES: MAY CAUSE BLINDNESS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHE, NAUSEA, GI DISTURBANCES

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
WATER. INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NECESSARY.
INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. NEVER TRY
TO MAKE A N UNCONSCIOUS PERSON VOMIT. IF CONSCIOUS GIVE 2
TABLESPOONS OF BAKING SODA IN A GLASS OF WATER & PRESS FINGERS TO
BACK OF TONGUE TO INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.

Flash Point:50F
Lower Limits:6
Upper Limits:36.5
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN A
FREEZER. KEEP AWAY FROM OXDIZERS & IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES
Supplemental Safety and Health

Boiling Pt:B.P. Text:149F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate & Reference:(ETHER=1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROGEN FLUORIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATINS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.